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Beilstein J. Org. Chem. 2021, 17, 1533–1564, doi:10.3762/bjoc.17.111
Graphical Abstract
Scheme 1: Representatives of isomeric bisoxindoles.
Scheme 2: Isoindigo-based OSCs with the best efficiency.
Scheme 3: Monoisoindigos with preferred 6,6'-substitution.
Scheme 4: Possibility of aromatic–quinoid structural transition.
Scheme 5: Isoindigo structures with incorporated acceptor nitrogen heterocycles.
Scheme 6: Monoisoindigos bearing pyrenyl substituents.
Scheme 7: p-Alkoxyphenylene-embedded thienylisoindigo with different acceptor anchor units.
Scheme 8: Nonfullerene OSC based on perylene diimide-derived isoindigo.
Scheme 9: Isoindigo as an additive in all-polymer OSCs.
Scheme 10: Bisisoindigos with different linker structures.
Scheme 11: Nonthiophene oligomeric monoisoindigos for OSCs.
Scheme 12: The simplest examples of polymers with a monothienylisoindigo monomeric unit.
Scheme 13: Monothienylisoindigos bearing π-extended electron-donor backbones.
Scheme 14: Role of fluorination and the molecular weight on OSC efficiency on the base of the bithiopheneisoin...
Scheme 15: Trithiopheneisoindigo polymers with variation in the substituent structure.
Scheme 16: Polymeric thienyl-linked bisisoindigos for OSCs.
Scheme 17: Isoindigo bearing the thieno[3,2-b]thiophene structural motif as donor component of OSCs.
Scheme 18: Thienylisoindigos with incorporated aromatic unit.
Scheme 19: One-component nonfullerene OSCs on the base of isoindigo.
Scheme 20: Isoindigo-based nonthiophene aza aromatic polymers as acceptor components of OSCs.
Scheme 21: Polymers with isoindigo substituent as side-chain photon trap.
Scheme 22: Isoindigo derivatives for OFET technology with the best mobility.
Scheme 23: Monoisoindigos as low-molecular-weight semiconductors.
Scheme 24: Polymeric bithiopheneisoindigos for OFET creation.
Scheme 25: Fluorination as a tool to improve isoindigo-based OFET devices.
Scheme 26: Diversely DPP–isoindigo-conjugated polymers for OFETs.
Scheme 27: Isoindigoid homopolymers with differing rigidity.
Scheme 28: Isoindigo-based materials with extended π-conjugation.
Scheme 29: Poly(isoindigothiophene) compounds as sensors for ammonia.
Scheme 30: Sensor devices based on poly(isoindigoaryl) compounds.
Scheme 31: Isoindigo polymers for miscellaneous applications.
Scheme 32: Mono-, rod-like, and polymeric isoindigos as agents for photoacoustic and photothermal cancer thera...
Beilstein J. Org. Chem. 2014, 10, 1121–1128, doi:10.3762/bjoc.10.111
Figure 1: Structures of the indolinone-substituted methanofullerenes prepared earlier.
Scheme 1: The two-step synthetic pathway towards the methanofullerenes AIM 1–9.
Figure 2: Optical absorption spectra of AIM 9, PCBM, and C60 in CH2Cl2 (2·10−5 mol·L−1, the cell thickness d ...
Figure 3: Cyclic voltammetry curve of AIM 9.
Figure 4: J–V characteristics of P3HT/AIMs and reference P3HT/PCBM devices for the P3HT/fullerene weight rati...
Figure 5: Absorption spectra of P3HT/fullerene blended films. The P3HT/PCBM blend was annealed during 15 min ...
Figure 6: AFM topography image of an as-casted 1:1 P3HT:AIM 7 blended film.